Dieterici equation of state

The Dieterici equation of state is given by

$p={\frac {RT}{v-b}}e^{-a/RTv}$

where (Eq. 8 in ):

$a={\frac {4R^{2}T_{c}^{2}}{P_{c}e^{2}}}$

and

$b={\frac {RT_{c}}{P_{c}e^{2}}}$

where $p$ is the pressure, $T$ is the temperature and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle R} is the molar gas constant. Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T_c} is the critical temperature and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle P_c} is the pressure at the critical point.

Sadus modification

Sadus proposed replacing the repulsive section of the Dieterici equation with the Carnahan-Starling equation of state, resulting in (Eq. 5):

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p = \frac{RT}{v} \frac{ 1 + \eta + \eta^2 - \eta^3 }{(1-\eta)^3 } e^{-a/RTv}}

where $\eta =b/4v$ is the packing fraction.