Hard disks

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Hard disks are hard spheres in two dimensions. The hard disk intermolecular pair potential is given by


\Phi_{12}\left( r \right) = \left\{ \begin{array}{lll}
\infty & ; & r <  \sigma \\
0      & ; & r \ge \sigma \end{array} \right.

where  \Phi_{12}\left(r \right) is the intermolecular pair potential between two disks at a distance r := |\mathbf{r}_1 - \mathbf{r}_2|, and σ is the diameter of the disk.

Contents

[edit] Phase transitions

Despite the apparent simplicity of this model/system, the phase behaviour and the nature of the phase transitions remains an area of active study. In a recent publication by Mak (Ref. 5) using over 4 million particles (20482) one appears to have the phase diagram isotropic (\rho \leq 0.890) hexatic (ρ > 0.920) solid.

[edit] Equations of state

Main article: Equations of state for hard disks

[edit] Virial coefficients

Main article: Hard sphere: virial coefficients

[edit] External links

[edit] References

  1. Nicholas Metropolis, Arianna W. Rosenbluth, Marshall N. Rosenbluth, Augusta H. Teller and Edward Teller, "Equation of State Calculations by Fast Computing Machines", Journal of Chemical Physics 21 pp.1087-1092 (1953)
  1. Ya G Sinai "Dynamical systems with elastic reflections", Russian Mathematical Surveys 25 pp. 137-189 (1970)
  2. Katherine J. Strandburg, John A. Zollweg, and G. V. Chester "Bond-angular order in two-dimensional Lennard-Jones and hard-disk systems", Physical Review B 30 pp. 2755 - 2759 (1984)
  3. Carl McBride and Carlos Vega "Fluid solid equilibrium for two dimensional tangent hard disk chains from Wertheim's perturbation theory", Journal of Chemical Physics 116 pp. 1757-1759 (2002)
  4. Nándor Simányi "Proof of the Boltzmann-Sinai ergodic hypothesis for typical hard disk systems", Inventiones Mathematicae 154 pp. 123-178 (2003)
  5. C. H. Mak "Large-scale simulations of the two-dimensional melting of hard disks", Physical Review E 73 065104(R) (2006)
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