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These are usually first-order phase transitions,
except at critical points, where they become second-order;
for supercritical points, the two phases become one.
Between the two phases in coexistence a liquid-vapour interface of molecular size is
formed.
[edit] References
- C. N. Yang and T. D. Lee "Statistical Theory of Equations of State and Phase Transitions. I. Theory of Condensation", Physical Review 87 pp. 404-409 (1952)