Wertheim's first order thermodynamic perturbation theory (TPT1): Difference between revisions
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*[http://dx.doi.org/10.1063/1.4947023 Bennett D. Marshall "Dual chain perturbation theory: A new equation of state for polyatomic molecules", Journal of Chemical Physics '''144''' 164104 (2016)] | |||
[[category:perturbation theory]] | [[category:perturbation theory]] |
Revision as of 13:31, 3 May 2016
Wertheim's first order thermodynamic perturbation theory (TPT1) [1] [2] [3] [4] [5] can be expressed as:
where is the equation of state of the monomer system and m is the number of monomers in the chains.
For example, in the study of the flexible hard sphere chain model one can use the Carnahan-Starling equation of state for , leading to
See also
References
- ↑ M. S. Wertheim "Fluids with highly directional attractive forces. I. Statistical thermodynamics" Journal of Statistical Physics 35 pp. 19-34 (1984)
- ↑ M. S. Wertheim "Fluids with highly directional attractive forces. II. Thermodynamic perturbation theory and integral equations" Journal of Statistical Physics 35 pp. 35-47 (1984)
- ↑ M. S. Wertheim "Fluids with highly directional attractive forces. III. Multiple attraction sites" Journal of Statistical Physics 42 pp. 459-476 (1986)
- ↑ M. S. Wertheim "Fluids with highly directional attractive forces. IV. Equilibrium polymerization" Journal of Statistical Physics 42 pp. 477-492 (1986)
- ↑ M. S. Wertheim "Thermodynamic perturbation theory of polymerization", Journal of Chemical Physics 87 pp. 7323-7331 (1987)
- Related reading