Glass transition: Difference between revisions
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Carl McBride (talk | contribs) m (Added heading for the glass transition pressure.) |
Carl McBride (talk | contribs) m (Changed references to Cite format) |
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*<math>\Delta V =0</math> | *<math>\Delta V =0</math> | ||
==Ideal glass transition temperature== | ==Ideal glass transition temperature== | ||
<ref>[http://dx.doi.org/10.1021/j100596a018 C. A. Angell and J. C. Tucker "Heat capacities and fusion entropies of the tetrahydrates of calcium nitrate, cadmium nitrate, and magnesium acetate. Concordance of calorimetric and relaxational ideal glass transition temperatures", Journal of Physical Chemistry '''78''' pp. 278 - 281 (1974)]</ref> | |||
==Observation time== | ==Observation time== | ||
<math>\tau_{\rm obs}</math> | <math>\tau_{\rm obs}</math> | ||
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*[[Kauzmann's paradox]] | *[[Kauzmann's paradox]] | ||
==References== | ==References== | ||
<references/> | |||
'''Related reading''' | |||
*[http://dx.doi.org/10.1103/RevModPhys.78.953 Jeppe C. Dyre "The glass transition and elastic models of glass-forming liquids", Reviews of Modern Physics '''78''' 953 (2006)] | |||
*[http://dx.doi.org/10.1063/1.2738471 Prabhat K. Gupta and John C. Mauro "The laboratory glass transition", Journal of Chemical Physics '''126''' 224504 (2007)] | |||
*[http://dx.doi.org/10.1146/annurev.physchem.58.032806.104653 Vassiliy Lubchenko and Peter G. Wolynes "Theory of Structural Glasses and Supercooled Liquids", Annual Review of Physical Chemistry '''58''' pp. 235-266 (2007)] | |||
*[http://dx.doi.org/10.1038/nmat2219 C. Patrick Royall, Stephen R. Williams, Takehiro Ohtsuka and Hajime Tanaka "Direct observation of a local structural mechanism for dynamic arrest", Nature Materials '''7''' pp. 556-561 (2008)] | |||
*[http://dx.doi.org/10.1063/1.2982172 Stephen R. Williams, Debra J. Searles, and Denis J. Evans "The glass transition and the Jarzynski equality", Journal of Chemical Physics '''129''' 134504 (2008)] | |||
*[http://dx.doi.org/10.1103/PhysRevLett.103.245701 Ning Xu, Thomas K. Haxton, Andrea J. Liu, and Sidney R. Nagel "Equivalence of Glass Transition and Colloidal Glass Transition in the Hard-Sphere Limit", Physical Review Letters '''103''' 245701 (2009)] | |||
[[category: Non-equilibrium thermodynamics]] | [[category: Non-equilibrium thermodynamics]] | ||
Revision as of 15:31, 16 August 2010
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In the laboratory the glass transition is not a sharp transition; its properties change smoothly across .
- increases with a decrease in the observation time, .
Ideal glass transition temperature
Observation time
Intrinsic average structural relaxation time
Pressure dependence of glass transition temperature
See also
References
Related reading
- Jeppe C. Dyre "The glass transition and elastic models of glass-forming liquids", Reviews of Modern Physics 78 953 (2006)
- Prabhat K. Gupta and John C. Mauro "The laboratory glass transition", Journal of Chemical Physics 126 224504 (2007)
- Vassiliy Lubchenko and Peter G. Wolynes "Theory of Structural Glasses and Supercooled Liquids", Annual Review of Physical Chemistry 58 pp. 235-266 (2007)
- C. Patrick Royall, Stephen R. Williams, Takehiro Ohtsuka and Hajime Tanaka "Direct observation of a local structural mechanism for dynamic arrest", Nature Materials 7 pp. 556-561 (2008)
- Stephen R. Williams, Debra J. Searles, and Denis J. Evans "The glass transition and the Jarzynski equality", Journal of Chemical Physics 129 134504 (2008)
- Ning Xu, Thomas K. Haxton, Andrea J. Liu, and Sidney R. Nagel "Equivalence of Glass Transition and Colloidal Glass Transition in the Hard-Sphere Limit", Physical Review Letters 103 245701 (2009)