Strongly correlating liquids

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Strongly correlating liquids are defined as those for whom R≥0.9 where (Eq. 6 [1])

R=⟨ΔVΔU⟩⟨(ΔV)2⟩⟨(ΔU)2⟩

where ΔU represents fluctuations of the potential in the NVT ensemble and V is the virial (see also Virial pressure).

Isomorphs[edit]

[2]

Lennard-Jones liquid[edit]

The liquid phase formed by the Lennard-Jones model is an example of a strongly correlating liquid[3].

References[edit]

Related reading