Critical exponents

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Reduced distance: Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \epsilon}

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \epsilon} is the reduced distance from the critical temperature, i.e.

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \epsilon = \left| 1 -\frac{T}{T_c}\right|}

Note that this implies a certain symmetry when the critical point is approached from either 'above' or 'below', which is not necessarily the case.

Heat capacity exponent: Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \alpha}

The isochoric heat capacity is given by Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle C_v}

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left. C_v\right.=C_0 \epsilon^{-\alpha}}

Theoretically one has Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \alpha = 0.1096(5)} [1] for the three dimensional Ising model, and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \alpha = -0.0146(8)} [2] for the three-dimensional XY universality class. Experimentally Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \alpha = 0.1105^{+0.025}_{-0.027}} [3].

Magnetic order parameter exponent: Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \beta}

The magnetic order parameter, Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle m} is given by

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left. m\right. = m_0 \epsilon^\beta}

Theoretically one has Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \beta =0.32653(10)} [1] for the three dimensional Ising model, and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \beta = 0.3485(2)} [2] for the three-dimensional XY universality class.

Susceptibility exponent: Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \gamma}

Susceptibility

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left. \chi \right. = \chi_0 \epsilon^{-\gamma}}

Theoretically one has Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \gamma = 1.2373(2)} [1] for the three dimensional Ising model, and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \gamma = 1.3177(5)} [2] for the three-dimensional XY universality class.

Correlation length

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left. \xi \right.= \xi_0 \epsilon^{-\nu}}

Theoretically one has Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \nu = 0.63012(16)} [1] for the three dimensional Ising model, and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \nu = 0.67155(27)} [2] for the three-dimensional XY universality class.

Inequalities

Fisher

Josephson inequality

The Josephson inequality [4][5][6]

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle d\nu \ge 2-\alpha}

Rushbrooke inequality

The Rushbrooke inequality (Eq. 2 [7]), based on the work of Essam and Fisher (Eq. 38 [8]) is given by

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \alpha + 2\beta + \gamma \ge 2} .

Using the above-mentioned values[1] one has:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle 0.1096 + (2\times0.32653) + 1.2373 = 1.99996}

Widom relation

Hyperscaling

Gamma divergence

When approaching the critical point along the critical isochore () the divergence is of the form

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left. \right. C_p \sim \kappa_T \sim (T-T_c)^{-\gamma} \sim (p-p_c)^{-\gamma}}

where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \gamma} is 1.0 for the Van der Waals equation of state, and is usually 1.2 to 1.3.

Epsilon divergence

When approaching the critical point along the critical isotherm the divergence is of the form

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left. \right. \kappa_T \sim (p-p_c)^{-\epsilon}}

where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \epsilon} is 2/3 for the Van der Waals equation of state, and is usually 0.75 to 0.8.

See also

References

  1. ↑ 1.0 1.1 1.2 1.3 1.4 Massimo Campostrini, Andrea Pelissetto, Paolo Rossi, and Ettore Vicari "25th-order high-temperature expansion results for three-dimensional Ising-like systems on the simple-cubic lattice", Physical Review E 65 066127 (2002)
  2. ↑ 2.0 2.1 2.2 2.3 Massimo Campostrini, Martin Hasenbusch, Andrea Pelissetto, Paolo Rossi, and Ettore Vicari "Critical behavior of the three-dimensional XY universality class" Physical Review B 63 214503 (2001)
  3. ↑ A. Haupt and J. Straub "Evaluation of the isochoric heat capacity measurements at the critical isochore of SF6 performed during the German Spacelab Mission D-2", Physical Review E 59 pp. 1795-1802 (1999)
  4. ↑ B. D. Josephson "Inequality for the specific heat: I. Derivation", Proceedings of the Physical Society 92 pp. 269-275 (1967)
  5. ↑ B. D. Josephson "Inequality for the specific heat: II. Application to critical phenomena", Proceedings of the Physical Society 92 pp. 276-284 (1967)
  6. ↑ Alan D. Sokal "Rigorous proof of the high-temperature Josephson inequality for critical exponents", Journal of Statistical Physics 25 pp. 51-56 (1981)
  7. ↑ G. S. Rushbrooke "On the Thermodynamics of the Critical Region for the Ising Problem", Journal of Chemical Physics 39, 842-843 (1963)
  8. ↑ John W. Essam and Michael E. Fisher "Padé Approximant Studies of the Lattice Gas and Ising Ferromagnet below the Critical Point", Journal of Chemical Physics 38, 802-812 (1963)
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