Supercooling and nucleation
|
This article is a 'stub' page, it has no, or next to no, content. It is here at the moment to help form part of the structure of SklogWiki. If you add sufficient material to this article then please remove the {{Stub-general}} template from this page. |
Supercooling and undercooling.
Homogeneous nucleation temperature
The homogeneous nucleation temperature (Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T_H} ) is the temperature below which it is almost impossible to avoid spontaneous and rapid freezing.
Szilard nucleation model
Zeldovich factor
See also
References
- Lawrence S. Bartell and David T. Wu "Do supercooled liquids freeze by spinodal decomposition?", Journal of Chemical Physics 127 174507 (2007)
- Pieter Rein ten Wolde, Maria J. Ruiz-Montero and Daan Frenkel "Numerical calculation of the rate of crystal nucleation in a Lennard-Jones system at moderate undercooling", Journal of Chemical Physics 104 pp. 9932-9947 (1996)
- Chantal Valeriani "Numerical studies of nucleation pathways of ordered and disordered phases", PhD Thesis (2007)
- Richard C. Flagan "A thermodynamically consistent kinetic framework for binary nucleation", Journal of Chemical Physics 127 214503 (2007)
Related reading
- Andrea Cavagna "Supercooled liquids for pedestrians", Physics Reports 476 pp. 51-124 (2009)
- Dimo Kashchiev "Nucleation", Butterworth-Heinemann (2000) ISBN 978-0-7506-4682-6