Chemical potential

Classical thermodynamics

Definition:

$\mu =\left.{\frac {\partial G}{\partial N}}\right\vert _{T,p}=\left.{\frac {\partial A}{\partial N}}\right\vert _{T,V}$

where $G$ is the Gibbs energy function, leading to

$\mu ={\frac {A}{Nk_{B}T}}+{\frac {pV}{Nk_{B}T}}$

where $A$ is the Helmholtz energy function, $k_{B}$ is the Boltzmann constant, $p$ is the pressure, $T$ is the temperature and $V$ is the volume.

Statistical mechanics

The chemical potential is the derivative of the Helmholtz energy function with respect to the number of particles

$\mu =\left.{\frac {\partial A}{\partial N}}\right\vert _{T,V}={\frac {\partial (-k_{B}T\ln Z_{N})}{\partial N}}=-k_{B}T\left[{\frac {3}{2}}\ln \left({\frac {2\pi mk_{B}T}{h^{2}}}\right)+{\frac {\partial \ln Q_{N}}{\partial N}}\right]$

where Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle Z_{N}} is the partition function for a fluid of $N$ identical particles

$Z_{N}=\left({\frac {2\pi mk_{B}T}{h^{2}}}\right)^{3N/2}Q_{N}$

and $Q_{N}$ is the configurational integral

$Q_{N}={\frac {1}{N!}}\int ...\int \exp(-U_{N}/k_{B}T)dr_{1}...dr_{N}$

Kirkwood charging formula

The Kirkwood charging formula is given by

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \beta \mu_{\rm ex} = \rho \int_0^1 d\lambda \int \frac{\partial \beta \Phi_{12} (r,\lambda)}{\partial \lambda} {\rm g}(r,\lambda) dr}

where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \Phi_{12}(r)} is the intermolecular pair potential and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle {\rm g}(r)} is the pair correlation function.

See also

• Ideal gas: Chemical potential
• Widom test-particle method
• Overlapping distribution method

References

Related reading

• G. Cook and R. H. Dickerson "Understanding the chemical potential", American Journal of Physics 63 pp. 737-742 (1995)
• T. A. Kaplan "The Chemical Potential", Journal of Statistical Physics 122 pp. 1237-1260 (2006)
• Federico G. Pazzona, Pierfranco Demontis, and Giuseppe B. Suffritti "Chemical potential evaluation in NVT lattice-gas simulations", Journal of Chemical Physics 137 154106 (2012)