Clausius equation of state: Difference between revisions

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The '''Clausius''' [[Equations of state | equation of state]] is given by <ref>[http://dx.doi.org/10.1002/andp.18802450302 R. Clausius "&Uuml;ber das Verhalten der Kohlens&auml;ure in Bezug auf Druck, Volumen und Temperatur", Annalen der Physik und Chemie '''9''' pp. 337-357 (1880)]</ref>  
The '''Clausius''' [[Equations of state | equation of state]], proposed in 1880 by [[Rudolf Julius Emanuel Clausius]] <ref>[http://dx.doi.org/10.1002/andp.18802450302 R. Clausius "&Uuml;ber das Verhalten der Kohlens&auml;ure in Bezug auf Druck, Volumen und Temperatur", Annalen der Physik und Chemie '''9''' pp. 337-357 (1880)]</ref> is given by (Equations 3 and 4 in <ref>[http://dx.doi.org/10.1021/ie50663a005 K. K. Shah and G. Thodos "A Comparison of Equations of State", Industrial & Engineering Chemistry '''57''' pp. 30-37 (1965)]</ref>)


:<math>\left[ p + \frac{a}{T(v+c)^2}\right] (v-b) =RT</math>
:<math>\left[ p + \frac{a}{T(v+c)^2}\right] (v-b) =RT</math>

Revision as of 10:01, 20 October 2009

The Clausius equation of state, proposed in 1880 by Rudolf Julius Emanuel Clausius [1] is given by (Equations 3 and 4 in [2])

[p+aT(v+c)2](v−b)=RT

where

a=vc−RTc4Pc
b=3RTc8Pc−vc

and

c=27R2Tc264Pc

where p is the pressure, T is the temperature, v is the volume per mol, and R is the molar gas constant. Tc is the critical temperature and Pc is the pressure at the critical point, and vc is the critical volume per mol.

References