Virial coefficients of model systems: Difference between revisions

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The virial equation of state is used to describe the behavior of diluted gases.
It is usually written as an expansion of the [[compresiblity factor]], <math> Z </math>, in terms of either the
density or the pressure. In the first case:
:<math> \frac{p V}{N k_B T } = Z = 1 + \sum_{k=2}^{\infty} B_k(T) \rho^{k-1}</math>.
where
* <math> p </math> is the pressure
*<math> V </math>  is the volume
*<math> N </math> is the number of molecules
*<math> \rho \equiv \frac{N}{V} </math> is the (number) density
*<math> B_k\left( T \right) </math> is called the k-th virial coefficient
== Systems ==


*[[hard sphere: virial equation of state|Hard spheres]]
*[[hard sphere: virial equation of state|Hard spheres]]

Revision as of 12:31, 21 March 2007