Song and Mason equation of state for hard convex bodies: Difference between revisions

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:<math>\frac{p}{\rho kT} \approx 1 + \frac{\eta}{(1-\eta)^3}\left((1+3\alpha)-(2+3\alpha-3\alpha^2)\eta + \left(1+\left[\left(\frac{B_4}{v_0^3}\right)_{HS} -12\right] \alpha -7\alpha^2\right)\eta^2\right)</math>
:<math>\frac{p}{\rho kT} \approx 1 + \frac{\eta}{(1-\eta)^3}\left((1+3\alpha)-(2+3\alpha-3\alpha^2)\eta + \left(1+\left[\left(\frac{B_4}{v_0^3}\right)_{HS} -12\right] \alpha -7\alpha^2\right)\eta^2\right)</math>
where <math>\eta</math> is the packing fraction, given by <math>\eta=\rho v_0</math>, and
where <math>\eta</math> is the [[packing fraction]], given by <math>\eta=\rho v_0</math> where <math>v_0</math> is the volume of one particle, and
:<math>\alpha= \frac{RS}{3V}</math>
:<math>\alpha= \frac{RS}{3v_0}</math>
where <math>V</math> is
where <math>S</math>, the surface area,  and <math>R</math> the mean radius of curvature.
the volume, <math>S</math>, the surface area,  and <math>R</math> the mean radius of curvature.
<math>\left(\frac{B_4}{v_0^3}\right)_{HS}</math> is the fourth [[Hard sphere: virial coefficients| virial coefficient]] for the [[hard sphere model]].   
<math>\left(\frac{B_4}{v_0^3}\right)_{HS}</math> is the fourth [[Hard sphere: virial coefficients| virial coefficient]] for the [[hard sphere model]].   
==References==
==References==
#[http://dx.doi.org/10.1103/PhysRevA.41.3121    Yuhua Song and E. A. Mason "Equation of state for a fluid of hard convex bodies in any number of dimensions", Physical Review A '''41''' pp. 3121 - 3124 (1990)]
#[http://dx.doi.org/10.1103/PhysRevA.41.3121    Yuhua Song and E. A. Mason "Equation of state for a fluid of hard convex bodies in any number of dimensions", Physical Review A '''41''' pp. 3121 - 3124 (1990)]
[[category: equations of state]]
[[category: equations of state]]

Revision as of 16:42, 3 August 2007

The Song and Mason equation of state (EOS) for hard convex bodies is given by (Eq. 25 of Ref. 1):

where is the packing fraction, given by where is the volume of one particle, and

where , the surface area, and the mean radius of curvature. is the fourth virial coefficient for the hard sphere model.

References

  1. Yuhua Song and E. A. Mason "Equation of state for a fluid of hard convex bodies in any number of dimensions", Physical Review A 41 pp. 3121 - 3124 (1990)