Song and Mason equation of state for hard convex bodies: Difference between revisions

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is given by (Eq. 25 of Ref. 1):
is given by (Eq. 25 of Ref. 1):


:<math>\frac{p}{\rho kT} \approx 1 + \frac{\eta}{(1-\eta)^3}\left((1+3\alpha)-(2+3\alpha-3\alpha^2)\eta + \left(1+\left[\frac{B_4}{v_0^3}_{HS} -12\right] \alpha -7\alpha^2\right)\eta^2\right)</math>
:<math>\frac{p}{\rho kT} \approx 1 + \frac{\eta}{(1-\eta)^3}\left((1+3\alpha)-(2+3\alpha-3\alpha^2)\eta + \left(1+\left[\left(\frac{B_4}{v_0^3}\right)_{HS} -12\right] \alpha -7\alpha^2\right)\eta^2\right)</math>
where <math>\eta</math> is the packing fraction, given by <math>\eta=\rho v_0</math>, and
where <math>\eta</math> is the packing fraction, given by <math>\eta=\rho v_0</math>, and
:<math>\alpha= \frac{RS}{3V}</math>
:<math>\alpha= \frac{RS}{3V}</math>
where <math>V</math> is
where <math>V</math> is
the volume, <math>S</math>, the surface area,  and <math>R</math> the mean radius of curvature.
the volume, <math>S</math>, the surface area,  and <math>R</math> the mean radius of curvature.
<math>\left(\frac{B_4}{v_0^3}\right)_{HS}</math> is the fourth [[Hard sphere: virial coefficients| virial coefficient]] for the [[hard sphere model]]. 
==References==
==References==
#[http://dx.doi.org/10.1103/PhysRevA.41.3121    Yuhua Song and E. A. Mason "Equation of state for a fluid of hard convex bodies in any number of dimensions", Physical Review A '''41''' pp. 3121 - 3124 (1990)]
#[http://dx.doi.org/10.1103/PhysRevA.41.3121    Yuhua Song and E. A. Mason "Equation of state for a fluid of hard convex bodies in any number of dimensions", Physical Review A '''41''' pp. 3121 - 3124 (1990)]
[[category: equations of state]]
[[category: equations of state]]

Revision as of 14:47, 3 August 2007

The Song and Mason equation of state (EOS) for hard convex bodies is given by (Eq. 25 of Ref. 1):

where is the packing fraction, given by , and

where is the volume, , the surface area, and the mean radius of curvature. is the fourth virial coefficient for the hard sphere model.

References

  1. Yuhua Song and E. A. Mason "Equation of state for a fluid of hard convex bodies in any number of dimensions", Physical Review A 41 pp. 3121 - 3124 (1990)