Rotational relaxation of water: Difference between revisions

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m (New page: {{Stub-water}} Rotational relaxation of water: {| border="1" |- | symbol || explanation || experimental value, and method |- | HH || H-H axis || <math>\tau_2=2.0</math>ps (...)
 
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| HH  || H-H axis  ||  <math>\tau_2=2.0</math>ps  (H-H dipolar relaxation NMR)
| HH  || H-H axis  ||  <math>\tau_2=2.0</math>ps  (H-H dipolar relaxation NMR)
|-   
|-   
| OH  || O-H axis  ||  <math>\tau_2=1.95</math>ps (<math>^{17}</math>O-H dipolar relaxation NMR)
| OH  || O-H axis  ||  <math>\tau_2=1.95</math>ps (<sup>17</sup>O-H dipolar relaxation NMR)
|-
|-
| <math>\mu</math> || dipolar axis || not measurable, but related to bulk dielectric relaxation
| <math>\mu</math> || dipolar axis || not measurable, but related to bulk dielectric relaxation

Latest revision as of 17:12, 24 October 2016

This article is a 'stub' about water and/or ice. It has no, or next to no, content. It is here at the moment to help form part of the structure of SklogWiki. If you add material to this article, remove the {{Stub-water}} template from this page.

Rotational relaxation of water:

symbol explanation experimental value, and method
HH H-H axis ps (H-H dipolar relaxation NMR)
OH O-H axis ps (17O-H dipolar relaxation NMR)
dipolar axis not measurable, but related to bulk dielectric relaxation
normal to the molecule plane not measurable

References[edit]

  1. David van der Spoel, Paul J. van Maaren, and Herman J. C. Berendsen "A systematic study of water models for molecular simulation: Derivation of water models optimized for use with a reaction field", J. Chem. Phys. 108 10220 (1998)