Ideal gas Helmholtz energy function: Difference between revisions

From SklogWiki
Jump to navigation Jump to search
No edit summary
m (defined a couple of terms)
 
Line 13: Line 13:
:<math>A=Nk_BT\left(\ln \Lambda^3 \rho -1 \right)</math>
:<math>A=Nk_BT\left(\ln \Lambda^3 \rho -1 \right)</math>


where <math>\Lambda</math>is the [[de Broglie thermal wavelength]] and <math>k_B</math> is the [[Boltzmann constant]].
[[Category:Ideal gas]]
[[Category:Ideal gas]]
[[Category:Statistical mechanics]]
[[Category:Statistical mechanics]]

Latest revision as of 12:19, 4 August 2008

From equations

for the canonical ensemble partition function for an ideal gas, and

for the Helmholtz energy function, one has

using Stirling's approximation

one arrives at

where is the de Broglie thermal wavelength and is the Boltzmann constant.