Gibbs phase rule: Difference between revisions
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Carl McBride (talk | contribs) (New page: '''Gibbs phase rule''' <ref>Josiah Willard Gibbs "On the Equilibrium of Heterogeneous Substances", Transactions of the Connecticut Academy '''III''' pp. 108-248 (1876) [http://gallica.bnf...) |
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where <math>F</math> is the number of [[intensive properties| intensive parameters]], <math>P</math> is the number of [[Phase diagrams | phases]] and <math>C</math> is the number of components. | where <math>F</math> is the number of [[intensive properties| intensive parameters]], <math>P</math> is the number of [[Phase diagrams | phases]] and <math>C</math> is the number of components. | ||
==Derivation== | ==Derivation== | ||
<ref>David Ruelle "Statistical mechanics: rigorous results" World Scientific Publishing (1969) § 7.5 (pp. 190-192) ISBN 978-981-02-3862-9</ref> | |||
<ref>[http://dx.doi.org/10.1007/BF02070248 G. Gutiérrez "Gibbs' phase rule revisited", Theoretical and Mathematical Physics '''108''' pp. 1222-1224 (1996)]</ref> | |||
==References== | ==References== | ||
<references/> | <references/> | ||
[[category: classical thermodynamics]] | [[category: classical thermodynamics]] | ||
Latest revision as of 16:15, 10 December 2009
Gibbs phase rule [1] [2] states that
where is the number of intensive parameters, is the number of phases and is the number of components.
Derivation[edit]
References[edit]
- ↑ Josiah Willard Gibbs "On the Equilibrium of Heterogeneous Substances", Transactions of the Connecticut Academy III pp. 108-248 (1876) (page images on gallica)
- ↑ Josiah Willard Gibbs "On the Equilibrium of Heterogeneous Substances", Transactions of the Connecticut Academy III pp. 343-524 (1878) (page images on gallica)
- ↑ David Ruelle "Statistical mechanics: rigorous results" World Scientific Publishing (1969) § 7.5 (pp. 190-192) ISBN 978-981-02-3862-9
- ↑ G. Gutiérrez "Gibbs' phase rule revisited", Theoretical and Mathematical Physics 108 pp. 1222-1224 (1996)