Gibbs energy function: Difference between revisions

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:<math>dG=\left(\frac{\partial G}{\partial T}\right)_p dT + \left(\frac{\partial G}{\partial p}\right)_T dp</math>
:<math>dG=\left(\frac{\partial G}{\partial T}\right)_p dT + \left(\frac{\partial G}{\partial p}\right)_T dp</math>
Good for use in the ''NpT'' ensemble.

Revision as of 19:12, 22 February 2007

Definition:


Taking the total derivative

From the Second law of thermodynamics one obtains

thus one arrives at


For G(T,p) we have the following total differential