Gibbs-Duhem relation: Difference between revisions

Latest revision as of 17:42, 29 January 2008

The Gibbs-Duhem relation is given by

SdT-Vdp+Nd\mu =0

or

\left.{\frac {\partial p}{\partial \mu }}\right\vert _{T}=\rho

where $p$ is the pressure, $S$ is the entropy, $V$ is the volume, $\mu$ is the chemical potential and $\rho$ is the number density.

@@ Line 1: / Line 1: @@
-:<math> \left.\frac{\partial P}{\partial \mu}\right\vert_{T}   = \rho</math>
+The '''Gibbs-Duhem relation''' is given by
+:<math>SdT -Vdp + Nd\mu =0</math>
+or
+:<math> \left.\frac{\partial p}{\partial \mu}\right\vert_{T}   = \rho</math>
+where <math>p</math> is the [[pressure]], <math>S</math> is the [[entropy]], <math>V</math> is the volume, <math>\mu</math> is the [[chemical potential]] and <math>\rho</math> is the number density.
+==See also==
+*[[Gibbs-Duhem integration]]
 [[Category: Classical thermodynamics]]