Dendrimers
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Dendrimers
Density profile
Dense shell model
Dense core model
Radius of gyration
It has been suggested that the radius of gyration () scales as [4]
where is the number of monomers.
Specific dendrimers
- Carbosilane
- PAMAM (also known as STARBURST®)
- PBzE poly(benzyl ether)
- PPI (polypropylenimine)
- Tecto dendrimers
References
- ↑ P. G. de Gennes and H. Hervet "Statistics of «starburst» polymers", Journal de Physique Lettres 44 pp. 351-360 (1983)
- ↑ Robert L. Lescanec , M. Muthukumar "Configurational characteristics and scaling behavior of starburst molecules: a computational study", Macromolecules 23 pp. 2280-2288 (1990)
- ↑ David Boris and Michael Rubinstein "A Self-Consistent Mean Field Model of a Starburst Dendrimer: Dense Core vs Dense Shell", Macromolecules 29 pp. 7251-7260 (1996)
- ↑ Michael Murat and Gary S. Grest "Molecular Dynamics Study of Dendrimer Molecules in Solvents of Varying Quality", Macromolecules 29 pp.1278–1285 (1996)
- Related reading
- Matthias Ballauff and Christos N. Likos "Dendrimers in Solution: Insight from Theory and Simulation", Angewandte Chemie International Edition 43 pp. 2998-3020 (2004)
- M. R. Wilson, J. M. Ilnytskyi, L. M. Stimson and Z. E. Hughes "Computer simulations of liquid crystal polymers and dendrimers" in Computer Simulations of liquid crystals and polymers, eds. Pasini P., Zannoni C. and Zŭmer S., Kluwer pp. 57-78 (2004) (preprint)
- Mark R. Wilson, Lorna M. Stimson and Jaroslav M. Ilnytskyi "The influence of lateral and terminal substitution on the structure of a liquid crystal dendrimer in nematic solution: A computer simulation study", Liquid Crystals 33 pp. 1167 - 1175 (2006)
- Juan J. Freire "Realistic numerical simulations of dendrimer molecules", Soft Matter 4 pp. 2139-2143 (2008)
- Gustavo Del Río Echenique, Ricardo Rodríguez Schmidt, Juan J. Freire, José G. Hernández Cifre and José García de la Torre "A Multiscale Scheme for the Simulation of Conformational and Solution Properties of Different Dendrimer Molecules", Journal of the American Chemical Society (JACS) 131 pp. 8548-8556 (2009)
- J. M. Ilnytskyi, J. S. Lintuvuori, M. R. Wilson "Simulation of bulk phases formed by polyphilic liquid crystal dendrimers", Condensed Matter Physics 13 pp. 33001:1-16 (2010)