Carnahan-Starling equation of state

The equation of Carnahan-Starling is an approximate equation of state for the fluid phase of the Hard Sphere model in three dimensions.

$Z={\frac {pV}{Nk_{B}T}}={\frac {1+\eta +\eta ^{2}-\eta ^{3}}{(1-\eta )^{3}}}.$

where:

• $p$ is the pressure

• $V$ is the volume

• $N$ is the number of particles

• $k_{B}$ is the Boltzmann constant

• Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T } is the absolute temperature

• Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \eta } is the packing fraction:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \eta = \frac{ \pi }{6} \frac{ N \sigma^3 }{V} }

• Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \sigma } is the Hard Sphere diameter

(please check the equation)

References

   N.F.Carnahan and K.E.Starling, J. Chem. Phys. 51 , 635-636 (1969)