Gibbs energy function

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Revision as of 18:09, 22 February 2007 by Carl McBride (talk | contribs) (New page: Definition: :<math>\left.G\right.=A+pV</math> :<math>\left.G\right.=U-TS+pV</math> Taking the total derivative :<math>\left.dG\right.=dU-TdS-SdT+pdV+Vdp</math> but from equation \ref...)
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Definition:


Taking the total derivative

but from equation \ref{secondlaw} we obtain

Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle \left.dG\right.=TdS-pdV-TdS-SdT+pdV+Vdp}

thus one arrives at


Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle \left.dG\right.=-SdT+Vdp}

For G(T,p) we have the following total differential


Good for $NpT$