Ideal gas: Energy

From SklogWiki
Revision as of 18:13, 7 June 2007 by Carl McBride (talk | contribs)
Jump to navigation Jump to search

The energy of the ideal gas is given by (Hill Eq. 4-16)

Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle E=-T^{2}\left.{\frac {\partial (A/T)}{\partial T}}\right\vert _{V,N}=kT^{2}\left.{\frac {\partial \ln Q}{\partial T}}\right\vert _{V,N}=NkT^{2}{\frac {d\ln T^{3/2}}{dT}}={\frac {3}{2}}NkT}

This energy is all kinetic energy, Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle 1/2.kT} per degree of freedom. This is because there are no intermolecular forces, thus no potential energy.

References

  1. Terrell L. Hill "An Introduction to Statistical Thermodynamics" 2nd Ed. Dover (1962)