Gibbs distribution

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Revision as of 10:55, 29 May 2007 by Carl McBride (talk | contribs) (New page: Ref 1 Eq. 3.37: :<math>\mathcal{G}_{(N)} = \frac{1}{Z_{(N)}} \exp \left( - \frac{H_{(N)}}{\Theta}\right)</math> where <math>N</math> is the number of particles, <math>H</math> is the [[H...)
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Ref 1 Eq. 3.37:

Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle {\mathcal {G}}_{(N)}={\frac {1}{Z_{(N)}}}\exp \left(-{\frac {H_{(N)}}{\Theta }}\right)}

where is the number of particles, is the Hamiltonian of the system and is the temperature (to convert into the more familiar Kelvin scale one divides by the Boltzmann constant Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle k_B} ). The constant Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle Z_{(N)}} is found from the normalization condition (Ref. 1 Eq. 3.38)

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \frac{1}{\Gamma_{(N)}^{(0)}Z_{(N)}} \int_V \exp \left( - \frac{U_1,..., _N}{\Theta}\right) ~{\rm d}^3r_1 ... {\rm d}^3r_N \int_{- \infty}^{\infty} \exp \left( - \frac{K_{(N)}}{\Theta}\right) ~{\rm d}^3p_1 ... {\rm d}^3p_N =1}

which leads to (Ref. 1 Eq. 3.40)

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle Z_{(N)}= \frac{1}{V^N} Q_{(N)}}

where (Ref. 1 Eq. 3.41)

Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle Q_{(N)}=\int _{V}\exp \left(-{\frac {U_{1},...,_{N}}{\Theta }}\right)~{\rm {d}}^{3}r_{1}...{\rm {d}}^{3}r_{N}}

this is the statistical integral

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle Z \equiv \sum_n e^{-E_n/T}= {\rm tr} ~ e^{-H|T}}

where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle H} is the Hamiltonian of the system.

References

  1. G. A. Martynov "Fundamental Theory of Liquids. Method of Distribution Functions", Adam Hilger (out of print)