Detailed balance

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Detailed balance (or the principle of microscopic reversibility) expresses the notion that at equilibrium, there are as many processes destroying situation Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle A} and creating situation Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle B} as there are processes destroying situation Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle B} and creating situation Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle A} (Ref 1 Appendix VII).

References

  1. D. Ter Haar "Foundations of Statistical Mechanics", Reviews of Modern Physics 27 pp. 289 - 338 (1955)
  2. Gilbert N. Lewis "A New Principle of Equilibrium", PNAS 11 pp. 179-183 (1925)