Clausius equation of state

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The Clausius equation of state is given by

where

Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle a=v_{c}-{\frac {RT_{c}}{4P_{c}}}}
Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle b={\frac {3RT_{c}}{8P_{c}}}-v_{c}}

and

Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle c={\frac {27R^{2}T_{c}^{2}}{64P_{c}}}}

where is the pressure, is the temperature and is the molar gas constant. Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T_c} is the critical temperature and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle P_c} is the pressure at the critical point.

References

  1. R. Clausius "Ueber das Verhalten der Kohlensäure in Bezug auf Druck, Volumen und Temperatur", Annalen der Physik und Chemie 9 pp. 337-357 (1880)