Gibbs energy function

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Revision as of 17:09, 22 February 2007 by Carl McBride (talk | contribs) (New page: Definition: :<math>\left.G\right.=A+pV</math> :<math>\left.G\right.=U-TS+pV</math> Taking the total derivative :<math>\left.dG\right.=dU-TdS-SdT+pdV+Vdp</math> but from equation \ref...)
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Definition:

G=A+pV


G=U−TS+pV

Taking the total derivative

dG=dU−TdS−SdT+pdV+Vdp

but from equation \ref{secondlaw} we obtain

dG=TdS−pdV−TdS−SdT+pdV+Vdp

thus one arrives at


dG=−SdT+Vdp

For G(T,p) we have the following total differential


dG=(∂G∂T)pdT+(∂G∂p)Tdp

Good for $NpT$