Enthalpy

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Revision as of 17:03, 22 February 2007 by Carl McBride (talk | contribs) (New page: Definition: :<math>\left.H\right.=U+pV</math> ''(-pV)'' is a ''conjugate pair''. The differential of this function is :<math>\left.dH\right.=dU+pdV+Vdp</math> but from equation \ref{se...)
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Definition:

H=U+pV

(-pV) is a conjugate pair. The differential of this function is

dH=dU+pdV+Vdp

but from equation \ref{secondlaw} we obtain

dH=TdS−pdV+pdV+Vdp

thus we arrive at

dH=TdS+Vdp

For H(S,p) we have the following total differential

dH=(∂H∂S)pdS+(∂H∂p)Sdp