Hard sphere model

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The hard sphere interaction potential is given by

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle V \left( r \right) = \left\{ \begin{array}{lll} \infty & ; & r < \sigma \\ 0 & ; & r \ge \sigma \end{array} \right. }


where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle V\left(r \right) } is the potential energy between two spheres at a distance , and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \sigma } is the sphere diameter.

Hard sphere fluid equation of state; See Carnahan-Starling (three dimensions)

Related systems

Hard disks in a 2-dimensional space

Hard rods in one dimension

Widom-Rowlinson model

Polydisperse hard spheres

Data

Virial coefficients of hard spheres and hard disks

References