Clausius equation of state

The Clausius equation of state is given by

$\left[p+{\frac {a}{T(v+c)^{2}}}\right](v-b)=RT$

where

$a={\frac {27R^{2}T_{c}^{2}}{64P_{c}}}$

$b=v_{c}-{\frac {RT_{c}}{4P_{c}}}$

and

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where $p$ is the pressure, $T$ is the temperature and $R$ is the molar gas constant. $T_{c}$ is the critical temperature and $P_{c}$ is the pressure at the critical point.

References

1. R. Clausius "Ueber das Verhalten der Kohlensäure in Bezug auf Druck, Volumen und Temperatur", Annalen der Physik und Chemie 9 pp. 337-357 (1880)