Dieterici equation of state
The Dieterici equation of state, proposed in 1899 (Ref. 1) is given by
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left. p(v-b) \right.= RT e^{-a/RTv}}
where
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle a = \frac{4R^2T_c^2}{P_ce^2}}
and
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle b=\frac{RT_c}{P_ce^2}}
References
- C. Dieterici, Ann. Phys. Chem. Wiedemanns Ann. 69, 685 (1899)
- K. K. Shah and G. Thodos "A Comparison of Equations of State", Industrial & Engineering Chemistry 57 pp. 30 - 37 (1965)
- Richard J. Sadus "Equations of state for fluids: The Dieterici approach revisited", Journal of Chemical Physics 115 pp. 1460-1462 (2001)