Triangular well model: Difference between revisions
Carl McBride (talk | contribs) m (New page: {{stub-general}} The '''triangular well model''' is given by :<math> \Phi\left( r \right) = \left\{ \begin{array}{ccc} \infty & ; & r \leq \sigma \\ \frac{\epsilon (r/\sigma - \lambda)}...) |
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where <math>\Phi(r)</math> is the [[intermolecular pair potential]], <math>r</math> is the distance, <math>\sigma</math> is the hard diameter, <math>\epsilon</math> is the well depth | where <math>\Phi(r)</math> is the [[intermolecular pair potential]], <math>r</math> is the distance, <math>\sigma</math> is the hard diameter, <math>\epsilon</math> is the well depth | ||
and λ > 1. | and λ > 1. | ||
==Equation of state== | |||
:''Main article: [[Equations of state for the triangular well model]]'' | |||
==Critical point== | |||
==References== | ==References== | ||
#[http://dx.doi.org/10.1139/p74-010 Damon N. Card and John Walkley "Monte Carlo and Perturbation Calculations for a Triangular Well Fluid", Canadian Journal of Physics '''52''' pp. 80-88 (1974)] | #[http://dx.doi.org/10.1139/p74-010 Damon N. Card and John Walkley "Monte Carlo and Perturbation Calculations for a Triangular Well Fluid", Canadian Journal of Physics '''52''' pp. 80-88 (1974)] | ||
#[http://dx.doi.org/10.1080/00268970701725013 F. F. Betancourt-Cárdenas, L. A. Galicia-Luna and S. I. Sandler "Thermodynamic properties for the triangular-well fluid", Molecular Physics '''105''' pp. 2987-2998 (2007)] | #[http://dx.doi.org/10.1080/00268970701725013 F. F. Betancourt-Cárdenas, L. A. Galicia-Luna and S. I. Sandler "Thermodynamic properties for the triangular-well fluid", Molecular Physics '''105''' pp. 2987-2998 (2007)] | ||
[[category: models]] | [[category: models]] | ||
Revision as of 11:37, 19 February 2008
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The triangular well model is given by
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \Phi\left( r \right) = \left\{ \begin{array}{ccc} \infty & ; & r \leq \sigma \\ \frac{\epsilon (r/\sigma - \lambda)}{(\lambda -1)} & ; &\sigma < r \leq \lambda \sigma \\ 0 & ; & r > \lambda \sigma \end{array} \right. }
where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \Phi(r)} is the intermolecular pair potential, Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle r} is the distance, Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \sigma} is the hard diameter, Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \epsilon} is the well depth and λ > 1.
Equation of state
- Main article: Equations of state for the triangular well model
Critical point
References
- Damon N. Card and John Walkley "Monte Carlo and Perturbation Calculations for a Triangular Well Fluid", Canadian Journal of Physics 52 pp. 80-88 (1974)
- F. F. Betancourt-Cárdenas, L. A. Galicia-Luna and S. I. Sandler "Thermodynamic properties for the triangular-well fluid", Molecular Physics 105 pp. 2987-2998 (2007)