Enthalpy: Difference between revisions

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m (New page: Definition: :<math>\left.H\right.=U+pV</math> ''(-pV)'' is a ''conjugate pair''. The differential of this function is :<math>\left.dH\right.=dU+pdV+Vdp</math> but from equation \ref{se...)
 
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:<math>\left.dH\right.=dU+pdV+Vdp</math>
:<math>\left.dH\right.=dU+pdV+Vdp</math>


but from equation \ref{secondlaw} we obtain
From the [[Second law of thermodynamics]] one obtains


:<math>\left.dH\right.=TdS -pdV +pdV+Vdp</math>
:<math>\left.dH\right.=TdS -pdV +pdV+Vdp</math>

Revision as of 18:04, 22 February 2007

Definition:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left.H\right.=U+pV}

(-pV) is a conjugate pair. The differential of this function is

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left.dH\right.=dU+pdV+Vdp}

From the Second law of thermodynamics one obtains

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left.dH\right.=TdS -pdV +pdV+Vdp}

thus we arrive at

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left.dH\right.=TdS +Vdp}

For H(S,p) we have the following total differential

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle dH=\left(\frac{\partial H}{\partial S}\right)_p dS + \left(\frac{\partial H}{\partial p}\right)_S dp}