Dipole moment: Difference between revisions

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The '''electric dipole moment''' is a measure of polarity. It is the second term in a multipole expansion of a field (the first one being the monopole, or Coulombic, term.) Its definition, for a system of point charges, is
The '''electric dipole moment''' is a measure of polarity. It is the second term in a multipole expansion of a field (the first one being the monopole, or Coulombic, term.) Its definition, for a system of point charges, is given by
<math>\mathbf{p} = \sum_{i=1}^N \, q_i \, \mathbf{r}_i.</math>
 
:<math>\mathbf{p} = \sum_{i=1}^N \, q_i \, \mathbf{r}_i.</math>


For molecular systems, it is customarily given in units of Debyes, after the physicist [[Peter J. W. Debye]].
For molecular systems, it is customarily given in units of Debyes, after the physicist [[Peter J. W. Debye]].

Revision as of 11:38, 5 June 2012

The electric dipole moment is a measure of polarity. It is the second term in a multipole expansion of a field (the first one being the monopole, or Coulombic, term.) Its definition, for a system of point charges, is given by

p=∑i=1Nqiri.

For molecular systems, it is customarily given in units of Debyes, after the physicist Peter J. W. Debye. In SI units, 1D equals approximately 3.33564×10−30 Coulomb-meter (exactly 10−21C m 2/s divided by c, the speed of light in vacuum). Conversely, 1 C m = 2.99791029D. This is unit is convenient for molecular systems since 1Å×1e=4.803D.