Gibbs energy function: Difference between revisions

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:<math>\left.G\right.=A+pV</math>
:<math>\left.G\right.=A+pV</math>
where ''p'' is the pressure, ''V'' is the volume, and  ''A'' is the [[Helmholtz energy function]], i.e.


:<math>\left.G\right.=U-TS+pV</math>
:<math>\left.G\right.=U-TS+pV</math>

Revision as of 14:52, 5 March 2007

Definition:

G=A+pV

where p is the pressure, V is the volume, and A is the Helmholtz energy function, i.e.

G=U−TS+pV

Taking the total derivative

dG=dU−TdS−SdT+pdV+Vdp

From the Second law of thermodynamics one obtains

dG=TdS−pdV−TdS−SdT+pdV+Vdp

thus one arrives at

dG=−SdT+Vdp

For G(T,p) we have the following total differential

dG=(∂G∂T)pdT+(∂G∂p)Tdp