Enthalpy: Difference between revisions

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:<math>\left.H\right.=U+pV</math>
:<math>\left.H\right.=U+pV</math>


''(-pV)'' is a ''conjugate pair''. The differential of this function is
where <math>U</math>  is the [[internal energy]], <math>p</math> is the [[pressure]], <math>V</math> is the volume and ''(-pV)'' is a ''conjugate pair''. The differential of this function is


:<math>\left.dH\right.=dU+pdV+Vdp</math>
:<math>\left.dH\right.=dU+pdV+Vdp</math>

Revision as of 15:19, 29 January 2008

Definition of the enthalpy, H

where is the internal energy, is the pressure, is the volume and (-pV) is a conjugate pair. The differential of this function is

From the Second law of thermodynamics one obtains

thus we arrive at

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left.dH\right.=TdS +Vdp}

For H(S,p) we have the following total differential

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle dH=\left(\frac{\partial H}{\partial S}\right)_p dS + \left(\frac{\partial H}{\partial p}\right)_S dp}