Widom-Rowlinson model: Difference between revisions

From SklogWiki
Jump to navigation Jump to search
No edit summary
No edit summary
Line 5: Line 5:
:<math> \Phi \left( r_{ij} \right) =  \Phi_{HS}(r_{ij});  </math> if <math> i </math> and <math> j</math> belong to different species,
:<math> \Phi \left( r_{ij} \right) =  \Phi_{HS}(r_{ij});  </math> if <math> i </math> and <math> j</math> belong to different species,


where <math> \Phi_{HS}(r) </math> is the [[hard sphere model | hard sphere]] pair potential
where <math> \Phi_{HS}(r) </math> is the [[hard sphere model | hard sphere]] [[intermolecular pair potential]].
==Surface tension==
==Surface tension==
*[http://dx.doi.org/10.1063/1.2751153 E. de Miguel, N. G. Almarza and G. Jackson "Surface tension of the Widom-Rowlinson model", Journal of Chemical Physics '''127''' 034707 (2007)]
*[http://dx.doi.org/10.1063/1.2751153 E. de Miguel, N. G. Almarza and G. Jackson "Surface tension of the Widom-Rowlinson model", Journal of Chemical Physics '''127''' 034707 (2007)]

Revision as of 14:29, 24 July 2007

The Widom-Rowlinson model (Ref. 1) for mixtures takes the form:

Φ(rij)=0; if i and j are particles of the same species
Φ(rij)=ΦHS(rij); if i and j belong to different species,

where ΦHS(r) is the hard sphere intermolecular pair potential.

Surface tension

References

  1. B. Widom and J. S. Rowlinson, "New Model for the Study of Liquid–Vapor Phase Transitions", J. Chem. Phys. 52, pp. 1670-1684 (1970)