Dieterici equation of state: Difference between revisions
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The Dieterici equation of state, proposed in 1899 (Ref. 1) is given by | The Dieterici equation of state, proposed in 1899 (Ref. 1) is given by | ||
:<math>\left. p(v-b) \right.= | :<math>\left. p(v-b) \right.= RT e^{-a/RTv}</math> | ||
where | where | ||
:<math>a = \frac{4R^2T_c^2}{P_ce^2}</math> | |||
and | |||
:<math>b=\frac{RT_c}{P_ce^2}</math> | |||
==References== | ==References== | ||
# C. Dieterici, Ann. Phys. Chem. Wiedemanns Ann. 69, 685 (1899) | # C. Dieterici, Ann. Phys. Chem. Wiedemanns Ann. 69, 685 (1899) | ||
#[http://dx.doi.org/10.1021/ie50663a005 K. K. Shah and G. Thodos "A Comparison of Equations of State", Industrial & Engineering Chemistry '''57''' pp. 30 - 37 (1965)] | |||
#[http://dx.doi.org/10.1063/1.1380711 Richard J. Sadus "Equations of state for fluids: The Dieterici approach revisited", Journal of Chemical Physics '''115''' pp. 1460-1462 (2001)] | #[http://dx.doi.org/10.1063/1.1380711 Richard J. Sadus "Equations of state for fluids: The Dieterici approach revisited", Journal of Chemical Physics '''115''' pp. 1460-1462 (2001)] | ||
[[category: equations of state]] | [[category: equations of state]] | ||
Revision as of 11:45, 8 June 2007
The Dieterici equation of state, proposed in 1899 (Ref. 1) is given by
where
and
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle b=\frac{RT_c}{P_ce^2}}
References
- C. Dieterici, Ann. Phys. Chem. Wiedemanns Ann. 69, 685 (1899)
- K. K. Shah and G. Thodos "A Comparison of Equations of State", Industrial & Engineering Chemistry 57 pp. 30 - 37 (1965)
- Richard J. Sadus "Equations of state for fluids: The Dieterici approach revisited", Journal of Chemical Physics 115 pp. 1460-1462 (2001)