First law of thermodynamics: Difference between revisions
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Conservation of energy. | Conservation of energy. | ||
:<math>dU=dQ+dW</math> | :<math>\left.dU\right.=dQ+dW</math> | ||
Where <math>U</math> is the internal energy of the system, i.e. | Where <math>U</math> is the internal energy of the system, i.e. | ||
| Line 8: | Line 8: | ||
of an external field. | of an external field. | ||
Reversible change | Reversible change | ||
:<math>dW=-PdV </math> | |||
:<math>\left.dW\right.=-PdV </math> | |||
irreversible change | irreversible change | ||
:<math>dW>-PdV </math> | |||
:<math>\left.dW\right. > -PdV </math> | |||
For an adiabatic system (i.e. a system in which no heat enters or leaves) | For an adiabatic system (i.e. a system in which no heat enters or leaves) | ||
then if two bodies of different temperatures are placed in contact | then if two bodies of different temperatures are placed in contact | ||
Revision as of 11:29, 23 February 2007
Conservation of energy.
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left.dU\right.=dQ+dW}
Where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle U} is the internal energy of the system, i.e. ignoring the external energy of the system, for example motion of the center of mass of the system, or the presence of an external field. Reversible change
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left.dW\right.=-PdV }
irreversible change
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left.dW\right. > -PdV }
For an adiabatic system (i.e. a system in which no heat enters or leaves) then if two bodies of different temperatures are placed in contact and then separated then the sum of the heat within the system is unchanged. This is conservation of energy. The first law of thermodynamics does not provide information on the direction of the heat transfer (if any). In other words, the common experience that the hotter object gives heat to the colder object, the direction of heat flow from hot to cold, is left to the second law of thermodynamics.