Pair stress approximation: Difference between revisions
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'''Pair stress approximation''' <ref>[http://dx.doi.org/10.1063/1.1669587 Emmanuel Meeron and Arnold J. F. Siegert "Statistical Mechanics of Hard‐Particle Systems", Journal of Chemical Physics '''48''' pp. 3139-3155 (1968)]</ref> (Eq. 3.18) | '''Pair stress approximation''' <ref>[http://dx.doi.org/10.1063/1.1669587 Emmanuel Meeron and Arnold J. F. Siegert "Statistical Mechanics of Hard‐Particle Systems", Journal of Chemical Physics '''48''' pp. 3139-3155 (1968)]</ref> for [[Idealised models#'Hard' models | hard particles]] is given by (Eq. 3.18) | ||
:<math>\rho B_2 = \frac{q}{(1+q)^{B_3}}</math> | :<math>\rho B_2 = \frac{q}{(1+q)^{B_3}}</math> | ||
Latest revision as of 15:35, 19 October 2011
Pair stress approximation [1] for hard particles is given by (Eq. 3.18)
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \rho B_2 = \frac{q}{(1+q)^{B_3}}}
where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle q= P/k_BT\rho -1} , Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle B_2} is the second virial coefficient and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle B_3} is the third virial coefficient.