Nematic phase

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Nematic phase for the hard 6x1x1 ellipsoid model.
Nematic phase for the hard 6x1x1 ellipsoid model.

The nematic phase has orientational order, but no positional order.

Contents

[edit] Discotic nematic phase

Discotic-nematic phase for the hard 6x6x1 ellipsoid model.
Discotic-nematic phase for the hard 6x6x1 ellipsoid model.

[edit] Dielectric tensor

In the uniaxial nematic phase, defining the z-axis to be parallel to the nematic axis, one has

\epsilon_{\alpha \beta}= \begin{pmatrix}
  \epsilon_\bot & 0               & 0 \\
  0             &  \epsilon_\bot  & 0 \\
  0             &  0              & \epsilon_\|
\end{pmatrix}

The anisotropy is defined as

\Delta \epsilon = \epsilon_\| - \epsilon_\bot .

The response of a nematic liquid crystal to an external electric field depends on both the sign and the magnitude of Δε.

[edit] Biaxial nematic phase

  1. Jorge Peláez and Mark R. Wilson "Atomistic Simulations of a Thermotropic Biaxial Liquid Crystal", Physical Review Letters 97 267801 (2006)
  2. Carl McBride and Enrique Lomba "Hard biaxial ellipsoids revisited: Numerical results", Fluid Phase Equilibria 255 pp. 37-45 (2007)
  3. Roberto Berardi, Luca Muccioli, and Claudio Zannoni "Field response and switching times in biaxial nematics", Journal of Chemical Physics 128 024905 (2008)

[edit] References

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