Inverse temperature

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It is often convenient to define a dimensionless inverse temperature, \beta:

\beta := \frac{1}{k_BT}

This notation likely comes from its origin as a Lagrangian multiplier, for which Greek letters are customarily written. Indeed, it shown in Ref. 1 (pp. 79-85) that this is the way it enters. The task is to maximize number of ways N particles may be assigned to K space-momentum cells, such that one has a set of occupation numbers n_i. Introducing the partition function:

\Omega\propto\frac{N!}{n_1! n_2! \ldots n_K!} ,

one could maximize its logarithm (a monotonous function):

\log \Omega \approx \log N -N - \sum_ i ( \log n_i + n_i) + \mathrm{consts} ,

where Stirling's approximation for large numbers has been used. The maximization must be performed subject to the constraint:

\sum_i n_i=N

An additional constraint, which applies only to dilute gases, is:

\sum_i n_i e_i=E,

where E is the total energy and e_i=p_i^2/2m is the energy of cell i. The method of Lagrange multipliers entails finding the extremum of the function

L=\log\Omega - \alpha (\sum_i n_i - N ) - \beta ( \sum_i n_i e_i - E  ),

where the two Lagrange multipliers enforce the two conditions and permit the treatment of the occupations as independent variables. The minimization leads to

n_i=C e^{-\beta e_i},

and an application to the case of an ideal gas reveals the connection with the temperature,

\beta := \frac{1}{k_BT} .

Similar methods are used for quantum statistics of dilute gases (Ref. 1, pp. 179-185).

References[edit]

  1. Kerson Huang, "Statistical Physics" John Wiley and Sons, second edition (1987) ISBN 978-0-471-81518-1