Editing Vega equation of state for hard ellipsoids
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The '''Vega''' | The '''Vega''' equation of state for an isotropic fluid of hard (biaxial) [[Hard ellipsoids |ellipsoids]] is given by (Ref. 1 Eq. 20): | ||
:<math> | :<math> | ||
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where <math>Z</math> is the [[compressibility factor]] and <math>y</math> is the [[volume fraction]], given by | where <math>Z</math> is the [[compressibility factor]] and <math>y</math> is the [[volume fraction]], given by | ||
<math>y= \rho V</math> where <math>\rho</math> is the [[number density]]. | <math>y= \rho V</math> where <math>\rho</math> is the [[number density]]. | ||
The | The virial coefficients are given by the fits | ||
:<math>B_3^* = 10 + 13.094756 \alpha' - 2.073909\tau' + 4.096689 \alpha'^2 | :<math>B_3^* = 10 + 13.094756 \alpha' - 2.073909\tau' + 4.096689 \alpha'^2 | ||
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where <math>V</math> is | where <math>V</math> is | ||
the volume, <math>S</math>, the surface area, and <math>R</math> the mean radius of curvature. | the volume, <math>S</math>, the surface area, and <math>R</math> the mean radius of curvature. | ||
For <math>B_2</math> see the page "[[Second virial coefficient]]". | For <math>B_2</math> see the page "[[Second virial coefficient]]". | ||
==References== | ==References== | ||
#[http://dx.doi.org/10.1080/002689797169934 Carlos Vega "Virial coefficients and equation of state of hard ellipsoids", Molecular Physics '''92''' pp. 651-665 (1997)] | |||
''' | #[http://dx.doi.org/10.1016/j.fluid.2007.03.026 Carl McBride and Enrique Lomba "Hard biaxial ellipsoids revisited: Numerical results", Fluid Phase Equilibria (2007)] | ||
[[category: equations of state]] | [[category: equations of state]] | ||
[[category: virial coefficients]] | [[category: virial coefficients]] | ||