Editing RSOZ
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Given and Stell | Given and Stell \cite{JCP_1992_97_04573,PA_1994_209_0495} provided {\bf exact} OZ equations for two-phase random media | ||
based on the original work of Madden and Glandt | based on the original work of Madden and Glandt \cite{JSP_1988_51_0537_nolotengoSpringer,JCP_1992_96_05422}.\\ | ||
For a two-species system, for the | For a two-species system, for the $(s+1)$ replicated system one has (see Eq.s 2.7 --2.11 \cite{PA_1994_209_0495}):\\ | ||
\begin{equation} | |||
h_{mm} = c_{mm} + \rho_m c_{mm} \otimes h_{mm} + s\rho_f c_{mf} \otimes h_{mf} | |||
\end{equation} | |||
\begin{equation} | |||
h_{mf} = c_{mf} + \rho_m c_{mm} \otimes h_{mf} + \rho_f c_{mf} \otimes h_{ff} + (s-1) \rho_f c_{mf} \otimes h_{12} | |||
\end{equation} | |||
\begin{equation} | |||
h_{fm} = c_{fm} + \rho_m c_{fm} \otimes h_{mm} + \rho_f c_{ff} \otimes h_{fm} + (s-1) \rho_f c_{12} \otimes h_{fm} | |||
\end{equation} | |||
\begin{equation} | |||
h_{ff} = c_{ff} + \rho_m c_{fm} \otimes h_{mf} + \rho_f c_{ff} \otimes h_{ff} + (s-1) \rho_f c_{12} \otimes h_{12} | |||
\end{equation} | |||
\begin{equation} | |||
h_{12} = c_{12} + \rho_m c_{fm} \otimes h_{mf} + \rho_f c_{ff} \otimes h_{12} + | |||
\rho_f c_{12} \otimes h_{ff} + (s-2) \rho_f c_{12} \otimes h_{12} | |||
In the limit of | \end{equation} | ||
In the limit of $s \rightarrow 0$ these equations from the ROZ equations (see Eq.s 2.12 --2.16 \cite{PA_1994_209_0495}):\\ | |||
\begin{equation} | |||
h_{mm} = c_{mm} + \rho_m c_{mm} \otimes h_{mm} | |||
\end{equation} | |||
\begin{equation} | |||
h_{mf} = c_{mf} + \rho_m c_{mm} \otimes h_{mf} + \rho_f c_{mf} \otimes h_{ff} - \rho_f c_{mf} \otimes h_{12} | |||
\end{equation} | |||
\begin{equation} | |||
h_{fm} = c_{fm} + \rho_m c_{fm} \otimes h_{mm} + \rho_f c_{ff} \otimes h_{fm} - \rho_f c_{12} \otimes h_{fm} | |||
\end{equation} | |||
\begin{equation} | |||
h_{ff} = c_{ff} + \rho_m c_{fm} \otimes h_{mf} + \rho_f c_{ff} \otimes h_{ff} - \rho_f c_{12} \otimes h_{12} | |||
\end{equation} | |||
\begin{equation} | |||
h_{12} = c_{12} + \rho_m c_{fm} \otimes h_{mf} + \rho_f c_{ff} \otimes h_{12} + | |||
\rho_f c_{12} \otimes h_{ff} -2 \rho_f c_{12} \otimes h_{12} | |||
\end{equation} | |||
When written in the `percolation terminology' | When written in the `percolation terminology' | ||
where | where $c$ terms `{\it connected}' and $b$ `{\it blocking}' are adapted from the | ||
language of percolation theory. | language of percolation theory. | ||
\begin{equation} | |||
h_{mm} = c_{mm} + \rho_m c_{mm} \otimes h_{mm} | |||
\end{equation} | |||
\begin{equation} | |||
h_{fm} = c_{fm} + \rho_m c_{fm} \otimes h_{mm} + \rho_f c_c \otimes h_{fm} | |||
\end{equation} | |||
\begin{equation} | |||
h_{ff} = c_{ff} + \rho_m c_{fm} \otimes h_{mf} + \rho_f c_c \otimes h_{ff} + \rho_f c_b \otimes h_c | |||
\end{equation} | |||
\begin{equation} | |||
h_c = c_c + \rho_f c_c \otimes h_c | |||
\end{equation} | |||
where the direct correlation function is split into | where the direct correlation function is split into | ||
\begin{equation} | |||
c_{ff}(12) = c_c (12) + c_b (12) | |||
\end{equation} | |||
and the total correlation function is also split into | and the total correlation function is also split into | ||
\begin{equation} | |||
h_{ff}(12)= h_c (12) + h_b(12) | |||
where | \end{equation} | ||
and | where $m$ denotes the matrix | ||
The blocking function | and $f$ denotes the fluid. | ||
fluid particles ``blocked" or separated from each other by matrix particles. | The blocking function $h_b(x)$ accounts for correlations between a pair of | ||
fluid particles ``blocked" or separated from each other by matrix particles.\\ | |||
IMPORTANT NOTE: Unlike an equilibrium mixture, there is only one convolution | IMPORTANT NOTE: Unlike an equilibrium mixture, there is only one convolution | ||
integral for | integral for $h_{mm}$ because the structure of the medium is | ||
unaffected by the presence of fluid particles. | unaffected by the presence of fluid particles.\\ | ||
Note: $C_{ff}$ (Madden and Glandt) $=h_c$ (Given and Stell)\\ | |||
Note: fluid: $f$ (Madden and Glandt), `1' (Given and Stell)\\ | |||
Note: matrix: $m$ (Madden and Glandt), `0' (Given and Stell)\\ | |||
At very low matrix porosities, i.e. very high densities of matrix particles, | At very low matrix porosities, i.e. very high densities of matrix particles, | ||
the volume accessible to fluid particles is divided into small cavities, each | the volume accessible to fluid particles is divided into small cavities, each | ||
totally surrounded by a matrix. In this limit, the function | totally surrounded by a matrix. In this limit, the function $h_c (x)$ | ||
describes correlations between fluid particles in the same cavity and the | describes correlations between fluid particles in the same cavity and the | ||
function | function $h_b(x)$ describes correlations between particles in different cavities. | ||