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| [[Water]] has a very rich [[phase diagrams | phase diagram]], complete with various unusual features, as well as at least [[Ice phases | fifteen ice phases]].
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| =Experimental=
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| The following are references for the experimental [[equations of state | equation of state]] of [[water]].
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| ==References== | | ==References== |
| #[http://dx.doi.org/10.1063/1.1749971 P. W. Bridgman "The phase diagram of water to 45,000 kg/cm<sup>2</sup>", Journal of Chemical Physics '''5''' pp. 964-966 (1937)] | | #[http://dx.doi.org/10.1063/1.1749971 P. W. Bridgman "The Phase Diagram of Water to 45,000 kg/cm2", Journal of Chemical Physics '''5''' pp. 964-966 (1937)] |
| #[http://dx.doi.org/10.1063/1.555787 A. Saul and W. Wagner "International Equations for the Saturation Properties of Ordinary Water Substance", Journal of Physical and Chemical Reference Data '''16''' pp. 893-901 (1987)]
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| #[http://dx.doi.org/10.1063/1.555812 H. Sato, M. Uematsu, K. Watanabe, A. Saul and W. Wagner "New International Skeleton Tables for the Thermodynamic Properties of Ordinary Water Substance", Journal of Physical and Chemical Reference Data '''17''' pp. 1439-1540 (1988)]
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| #[http://dx.doi.org/10.1063/1.555836 A. Saul and W. Wagner "A Fundamental Equation for Water Covering the Range from the Melting Line to 1273 K at Pressures up to 25 000 MPa", Journal of Physical and Chemical Reference Data '''18''' pp. 1537-1564 (1989)]
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| #[http://dx.doi.org/10.1063/1.555894 H. Sato, K. Watanabe, J. M. H. Levelt Sengers, J. S. Gallagher, P. G. Hill, J. Straub and W. Wagner "Sixteen Thousand Evaluated Experimental Thermodynamic Property Data for Water and Steam", Journal of Physical and Chemical Reference Data '''20''' pp. 1023-1044 (1991)]
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| #[http://dx.doi.org/10.1063/1.555926 Wolfgang Wagner and A. Pruss "International Equations for the Saturation Properties of Ordinary Water Substance. Revised According to the International Temperature Scale of 1990. Addendum to J. Phys. Chem. Ref. Data 16, 893 (1987)", Journal of Physical and Chemical Reference Data '''22''' pp. 783-787 (1993)]
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| #[http://dx.doi.org/10.1063/1.555947 Wolfgang Wagner, A. Saul, and A. Pruss "International Equations for the Pressure Along the Melting and Along the Sublimation Curve of Ordinary Water Substance", Journal of Physical and Chemical Reference Data '''23''' pp. 515-527 (1994)]
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| #[http://dx.doi.org/10.1063/1.1461829 W. Wagner and A. Pruß "The IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use", Journal of Physical and Chemical Reference Data '''31''' pp. 387-535 (2002)]
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| #[http://jchemed.chem.wisc.edu/journal/issues/2009/May/abs566.html A. Herráez, R. M. Hanson, and L. Glasser "Interactive 3D phase diagrams using Jmol", Journal of Chemical Education '''86''' pp. 566- (2009)] and [http://biomodel.uah.es/Jmol/plots/phase-diagrams/ website]
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| # [http://jchemed.chem.wisc.edu/Journal/Issues/2004/Mar/abs414.html L. Glasser "Water, water, everywhere: Phase diagrams of ordinary water substance", Journal of Chemical Education '''81''' pp. 414-418 (2004)]
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| =Theoretical=
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| [[Computer simulation techniques]] have now reached the stage where it is possible to calculate the entire phase diagram for a particular [[Water models | model of water]]. For example, see Ref <ref>[http://dx.doi.org/10.1103/PhysRevLett.92.255701 E. Sanz, C. Vega, J. L. F. Abascal, and L. G. MacDowell "Phase diagram of water from computer simulation", Physical Review Letters '''92''' 255701 (2004)]</ref>
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| ==TIP4P/2005 model==
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| [[Image:TIP4P_2005_phase_diagram.png|right|400px]]
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| The [[Phase diagrams | phase diagram]] of the [[TIP4P/2005]] model is given in a publication by Abascal, Sanz and Vega.
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| *[http://dx.doi.org/10.1039/b812832d Jose L. F. Abascal, Eduardo Sanz and Carlos Vega "Triple points and coexistence properties of the dense phases of water calculated using computer simulation", Physical Chemistry Chemical Physics '''11''' pp. 556-562 (2009)]
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| and for negative [[pressure]]s in the publication
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| *[http://dx.doi.org/10.1063/1.3182727 M. M. Conde, C. Vega, G. A. Tribello, and B. Slater "The phase diagram of water at negative pressures: Virtual ices", Journal of Chemical Physics '''131''' 034510 (2009)]
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| ====Liquid-vapour equilibria====
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| *[http://dx.doi.org/10.1063/1.2215612 C. Vega, J. L. F. Abascal and I. Nezbeda "Vapor-liquid equilibria from the triple point up to the critical point for the new generation of TIP4P-like models: TIP4P/Ew, TIP4P/2005, and TIP4P/ice" Journal of Chemical Physics '''125''' 034503 (2006)]
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| ====Plastic crystal phases====
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| Recent simulations have suggested the possibility of a [[Plastic crystals | plastic crystal]] phase or phases for water.
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| *[http://dx.doi.org/10.1039/b812834k J. L. Aragones, M. M. Conde, E. G. Noya and C. Vega "The phase diagram of water at high pressures as obtained by computer simulations of the TIP4P/2005 model: the appearance of a plastic crystal phase", Physical Chemistry Chemical Physics '''11''' pp. 543- (2009)]
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| *[http://dx.doi.org/10.1063/1.3156856 J. L. Aragones and C. Vega "Plastic crystal phases of simple water models", Journal of Chemical Physics '''130''' 244504 (2009)]
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| =References=
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| <references/>
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| =External links=
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| *[http://www.iapws.org/ The International Association for the Properties of Water and Steam]
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| [[category:phase diagrams]] | | [[category:phase diagrams]] |
| [[category:water]] | | [[category:water]] |
| [[category: equations of state]]
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