Editing Percus Yevick

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If one defines a class of [[cluster diagrams | diagrams]] by the linear combination (Eq. 5.18 Ref.1)
If one defines a class of diagrams by the linear combination (Eq. 5.18 Ref.1)
(See G. Stell in Ref. 2)
(See G. Stell in Ref. 2)


:<math>\left.D(r)\right. = y(r) + c(r) -g(r)</math>
:<math>\left.D(r)\right. = y(r) + c(r) -g(r)</math>


one has the exact [[integral equations | integral equation]]
one has the exact integral equation


:<math>y(r_{12}) - D(r_{12}) = 1 + n \int (f(r_{13})y(r_{13})+D(r_{13})) h(r_{23})~dr_3</math>
:<math>y(r_{12}) - D(r_{12}) = 1 + n \int (f(r_{13})y(r_{13})+D(r_{13})) h(r_{23})~dr_3</math>
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:<math>\left.h-c\right.=y-1</math>
:<math>\left.h-c\right.=y-1</math>


The Percus-Yevick [[Closure relations | closure relation]] can be written as (Ref. 3  Eq. 61)
The ''PY'' closure can be written as (Ref. 3  Eq. 61)


:<math>\left.f [ \gamma (r) ]\right. = [e^{-\beta \Phi} -1][\gamma (r) +1]</math>
:<math>\left.f [ \gamma (r) ]\right. = [e^{-\beta \Phi} -1][\gamma (r) +1]</math>
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:<math>\left.g(r)\right. = e^{-\beta \Phi} (1+ \gamma(r))</math>
:<math>\left.g(r)\right. = e^{-\beta \Phi} (1+ \gamma(r))</math>


where <math>\Phi(r)</math> is the [[intermolecular pair potential]].
or in terms of the bridge function
 
In terms of the [[bridge function]]


:<math>\left.B(r)\right.= \ln (1+\gamma(r) ) - \gamma(r)</math>
:<math>\left.B(r)\right.= \ln (1+\gamma(r) ) - \gamma(r)</math>
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Note: the restriction <math>-1 < \gamma (r) \leq 1</math> arising from the logarithmic term Ref. 6.
Note: the restriction <math>-1 < \gamma (r) \leq 1</math> arising from the logarithmic term Ref. 6.
A critical look at the PY was undertaken by  Zhou and Stell in Ref. 7.
A critical look at the PY was undertaken by  Zhou and Stell in Ref. 7.
==See also==
 
*[[Exact solution of the Percus Yevick integral equation for hard spheres]]
==References==
==References==
#[http://dx.doi.org/10.1088/0034-4885/28/1/306 J. S. Rowlinson "The equation of state of dense systems", Reports on Progress in Physics '''28''' pp. 169-199 (1965)]
#[http://dx.doi.org/10.1088/0034-4885/28/1/306 J. S. Rowlinson "The equation of state of dense systems", Reports on Progress in Physics '''28''' pp. 169-199 (1965)]
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