Liu hard sphere equation of state

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Hongqin Liu proposed a correction to the C-S EOS which improved accuracy by almost two order of magnitude [1]:


Z =  \frac{ 1 + \eta + \eta^2 -  \frac{8}{13}\eta^3 - \eta^4 + \frac{1}{2}\eta^5 }{(1-\eta)^3 }.

The conjugate virial coefficient correlation is given by:


B_n =  0.9423n^2 + 1.28846n - 1.84615, n > 3.
  1. [1]
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