Editing Intermolecular pair potential
Jump to navigation
Jump to search
The edit can be undone. Please check the comparison below to verify that this is what you want to do, and then publish the changes below to finish undoing the edit.
Latest revision | Your text | ||
Line 1: | Line 1: | ||
In general, the [[intermolecular pair potential]] for axially symmetric molecules, <math>\Phi_{12} </math>, is a function of five coordinates: | In general, the [[intermolecular pair potential]] for axially symmetric molecules, <math>\Phi_{12} </math>, is a function of five coordinates: | ||
Line 15: | Line 10: | ||
:<math>\left. \Phi_{12} \right. = 4\pi \sum_{L_1 L_2 m} L_1 L_2 m (r) Y_{L_1}^m (\theta_1, \phi_1) Y_{L_2}^m * (\theta_2, \phi_2)</math>, | :<math>\left. \Phi_{12} \right. = 4\pi \sum_{L_1 L_2 m} L_1 L_2 m (r) Y_{L_1}^m (\theta_1, \phi_1) Y_{L_2}^m * (\theta_2, \phi_2)</math>, | ||
where <math> | where <math>Y_{L m}(\theta, \phi)</math> are the [[spherical harmonics]]. | ||
==References== | ==References== | ||
#[http://dx.doi.org/10.1098/rspa.1954.0044 J. A. Pople "The Statistical Mechanics of Assemblies of Axially Symmetric Molecules. I. General Theory", Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences '''221''' pp. 498-507 (1954)] | #[http://dx.doi.org/10.1098/rspa.1954.0044 J. A. Pople "The Statistical Mechanics of Assemblies of Axially Symmetric Molecules. I. General Theory", Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences '''221''' pp. 498-507 (1954)] | ||
[[category: statistical mechanics]] | [[category: statistical mechanics]] |