Editing Grand canonical ensemble
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== Ensemble variables == | == Ensemble variables == | ||
* Chemical Potential, <math> \left. \mu \right. </math> | |||
:<math> \ | * Volume, <math> \left. V \right. </math> | ||
* Temperature, <math> \left. T \right. </math> | |||
== Partition Function == | |||
''Classical'' partition function (one-component system) in a three-dimensional space: <math> Q_{\mu VT} </math> | |||
:<math> Q_{\mu VT} = \sum_{N=0}^{\infty} \frac{ \exp \left[ \beta \mu N \right] V^N}{N! \Lambda^{3N} } \int d (R^*)^{3N} \exp \left[ - \beta U \left( V, (R^*)^{3N} \right) \right] </math> | |||
where: | where: | ||
* <math>N</math> is the number of particles | *<math> \left. N \right. </math> is the number of particles | ||
* <math> \left. \Lambda \right. </math> is the [[de Broglie thermal wavelength]] (which depends on the temperature) | * <math> \left. \Lambda \right. </math> is the [[de Broglie thermal wavelength]] (which depends on the temperature) | ||
* <math> \beta </math> | |||
* <math>U</math> is the potential energy, which depends on the coordinates of the particles (and on the | * <math> \beta = \frac{1}{k_B T} </math>, with <math> k_B </math> being the [[Boltzmann constant]] | ||
* <math> \left. U \right. </math> is the potential energy, which depends on the coordinates of the particles (and on the interaction model) | |||
* <math> \left( R^*\right)^{3N} </math> represent the <math>3N</math> position coordinates of the particles (reduced with the system size): i.e. <math> \int d (R^*)^{3N} = 1 </math> | * <math> \left( R^*\right)^{3N} </math> represent the <math>3N</math> position coordinates of the particles (reduced with the system size): i.e. <math> \int d (R^*)^{3N} = 1 </math> | ||
== | == Free energy and Partition Function == | ||
The corresponding thermodynamic | |||
(THis subsection should be checked) | |||
The corresponding thermodynamic potentail for the [[Grand canonical partition function | grand canonical partition function]] is: | |||
: <math> \left. A - \mu N \right. </math>, i.e.: | |||
:<math> \left. p V = k_B T \ | :<math> \left. p V = k_B T \log Q_{\mu V T } \right. </math> | ||
[[Category:Statistical mechanics]] | [[Category:Statistical mechanics]] |