Editing Frenkel line
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The '''Frenkel line''' is a line of change of | The '''Frenkel line''' is a line of change of microscopic dynamics of | ||
fluids. Below the Frenkel line the fluids are "rigid" and | fluids. Below the Frenkel line the fluids are "rigid" and | ||
"solid-like" while above it fluids are "soft" and "gas-like". | "solid-like" while above it fluids are "soft" and "gas-like". | ||
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of transverse excitations is <math> 1 k_B </math>. Therefore at the Frenkel | of transverse excitations is <math> 1 k_B </math>. Therefore at the Frenkel | ||
line, where transverse excitations vanish, the isochoric heat | line, where transverse excitations vanish, the isochoric heat | ||
capacity per particle should be <math> c_V=2 k_B </math | capacity per particle should be <math> c_V=2 k_B </math>. | ||
Crossing the Frenkel line leads also to some structural | Crossing the Frenkel line leads also to some structural changes in fluids | ||
<ref>[http://dx.doi.org/10.1063/1.4844135 Dima Bolmatov, V. V. Brazhkin, Yu. D. Fomin, V. N. Ryzhov, and K. Trachenko "Evidence for structural crossover in the supercritical state", Journal of Chemical Physics '''139''' 234501 (2013 | <ref> [http://dx.doi.org/10.1063/1.4844135 Dima Bolmatov, V. V. Brazhkin, Yu. D. Fomin, V. N. Ryzhov, and K. Trachenko "Evidence for structural crossover in the supercritical state", Journal of Chemical Physics '''139''' 234501 (2013)]</ref>. | ||
Currently Frenkel lines of several [[Idealised models|idealised liquids]], such as [[Lennard-Jones model|Lennard-Jones]] and [[Soft sphere potential|soft spheres]] | Currently Frenkel lines of several [[Idealised models|idealised liquids]], such as [[Lennard-Jones model|Lennard-Jones]] and [[Soft sphere potential|soft spheres]] | ||
<ref name="ufn"> </ref>, <ref name="frpre"> </ref>, <ref name="frprl"> </ref> | <ref name="ufn"> </ref>, <ref name="frpre"> </ref>, <ref name="frprl"> </ref> | ||
as well as [[realistic models]] such as | as well as [[realistic models]] such as | ||
[[iron|liquid iron]] <ref>[http://dx.doi.org/10.1038/srep07194 Yu. D. Fomin, V. N. Ryzhov, E. N. Tsiok, V. V. Brazhkin, and K. Trachenko "Dynamic transition in supercritical iron", Scientific Reports '''4''' 7194 (2014)]</ref>, | [[iron|liquid iron]] <ref>[http://dx.doi.org/10.1038/srep07194 Yu. D. Fomin, V. N. Ryzhov, E. N. Tsiok, V. V. Brazhkin, and K. Trachenko "Dynamic transition in supercritical iron", Scientific Reports '''4''' 7194 (2014)]</ref>, | ||
[[hydrogen]] <ref> [http://dx.doi.org/10.1103/PhysRevE.89.032126 K. Trachenko, V. V. Brazhkin, and D. Bolmatov, "Dynamic transition of supercritical hydrogen: Defining the boundary between interior and atmosphere in gas giants", Physical Review E '''89''' 032126 (2014)]</ref>, | [[hydrogen]] <ref> [http://dx.doi.org/10.1103/PhysRevE.89.032126 K. Trachenko, V. V. Brazhkin, and D.Bolmatov, "Dynamic transition of supercritical hydrogen: Defining the boundary between interior and atmosphere in gas giants", Physical Review E '''89''' 032126 (2014)]</ref>, | ||
[[water]] <ref name="kostya3"> [http://dx.doi.org/10.1103/PhysRevE.91.012112 C. Yang, V. V. Brazhkin, M. T. Dove, and K. Trachenko "Frenkel line and solubility maximum in supercritical fluids", Physical Review E '''91''' 012112 (2015)]</ref>, | [[water]] <ref name="kostya3"> [http://dx.doi.org/10.1103/PhysRevE.91.012112 C. Yang, V. V. Brazhkin, M. T. Dove, and K. Trachenko "Frenkel line and solubility maximum in supercritical fluids", Physical Review E '''91''' 012112 (2015)]</ref>, | ||
[[carbon dioxide]] | [[carbon dioxide]] <ref name="kostya3"> </ref>, | ||
and [[methane]] <ref name="kostya3"> </ref> | and [[methane]] <ref name="kostya3"> </ref> | ||
have been reported in the literature. | have been reported in the literature. | ||
==Related Lines== | ==Related Lines== |