Editing Crooks fluctuation theorem
Jump to navigation
Jump to search
The edit can be undone. Please check the comparison below to verify that this is what you want to do, and then publish the changes below to finish undoing the edit.
Latest revision | Your text | ||
Line 1: | Line 1: | ||
The '''Crooks fluctuation theorem''' was developed by Gavin E. Crooks. It is also known as the ''Crooks Identity'' or the ''Crooks fluctuation relation''. It is given by ( | {{Stub-general}} | ||
The '''Crooks fluctuation theorem''' was developed by Gavin E. Crooks. It is also known as the ''Crooks Identity'' or the ''Crooks fluctuation relation''. It is given by (Ref. 1 Eq. 2): | |||
Line 5: | Line 6: | ||
where <math>\omega</math> is the [[entropy]] production, <math>P_F(\omega)</math> is the "forward" probability distribution of this entropy production, and <math>P_R(-\omega)</math>, time-reversed. This expression can be written in terms of [[work]] (<math>W</math>) (Eq. 11): | where <math>\omega</math> is the [[entropy]] production, <math>P_F(\omega)</math> is the "forward" probability distribution of this entropy production, and <math>P_R(-\omega)</math>, time-reversed. This expression can be written in terms of [[work]] (<math>W</math>) (Ref. 1 Eq. 11): | ||
Line 12: | Line 13: | ||
where <math>\beta := 1/(k_BT)</math> where <math>k_B</math> is the [[Boltzmann constant]] and <math>T</math> is the [[temperature]], and <math>A</math> is the [[Helmholtz energy function]]. | where <math>\beta := 1/(k_BT)</math> where <math>k_B</math> is the [[Boltzmann constant]] and <math>T</math> is the [[temperature]], and <math>A</math> is the [[Helmholtz energy function]]. | ||
==References== | ==References== | ||
#[http://dx.doi.org/10.1103/PhysRevE.60.2721 Gavin E. Crooks "Entropy production fluctuation theorem and the nonequilibrium work relation for free energy differences", Physical Review E '''60''' pp. 2721 - 2726 (1999)] | |||
#[http://dx.doi.org/10.1063/1.2978949 L. Y. Chen "On the Crooks fluctuation theorem and the Jarzynski equality", Journal of Chemical Physics '''129''' 091101 (2008)] | |||
#[http://dx.doi.org/10.1063/1.3067878 Riccardo Chelli "Nonequilibrium work relations for systems subject to mechanical and thermal changes", Journal of Chemical Physics '''130''' 054102 (2009)] | |||
[[category:Non-equilibrium thermodynamics]] | [[category:Non-equilibrium thermodynamics]] | ||
[[category: fluctuation theorem]] | [[category: fluctuation theorem]] |